Monday, September 21, 2009
CALPHAD (Calculation of Phase Diagrams) - A Comprehensive Guide
This excellent book is probably the first comprehensive guide to the CALPHAD method. CALPHAD is an acronym that was coined in the early 1970s and stands for CALculation of PHAse Diagrams. The book covers the history of the CALPHAD method; the laws and basic concepts of thermodynamics (enthalpy, heat capacity, chemical equilibrium, Gibbs energy, etc); various experimental techniques to measure thermodynamic quantities and to construct phase diagrams; thermodynamic models for solutions and compound phases (stoichiometric compounds, random substitutional models, sublattice models, ionic liquid models, and aqueous solutions); phase stabilities; short-range and long-range ordering models; the role of magnetic Gibbs energy; computational methods and thermodynamic optimization of phase diagrams; as well as the coupling of thermodynamics and kinetics.
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